Production of gaseous olefins by catalytic conversion of hydrocarbons

Various fractions of petroleum, including residual oils and crude oils, are catalytically converted to produce gaseous olefins, especially propylene and butylene, in fluidized or moving bed reactors with solid acidic catalysts in the presence of steam at a temperature of 500 DEG C to 650 DEG C and a...

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Hauptverfasser: ZAITING, LI, SHUNHUA, LIU, XINGPIN, GE
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:Various fractions of petroleum, including residual oils and crude oils, are catalytically converted to produce gaseous olefins, especially propylene and butylene, in fluidized or moving bed reactors with solid acidic catalysts in the presence of steam at a temperature of 500 DEG C to 650 DEG C and a pressure of 1.5 x 10 Pa to 3 x 10 Pa, with a weight space velocity of 0.2 to 20 hr and a catalyst-to-oil ratio of 2 to 12. Spent catalyst is continuously removed from the reactor to a regenerator where the coke is burned off and then the hot catalyst returned to the reactor. Comparing with the conventional catalytic cracking and tubular furnace pyrolysis process, the present invention produces more propylene and butylene, their total yield is about 40 per cent by weight of the feedstock.