POLYIMIDES AND HEAT-RESISTANT ADHESIVES COMPRISING THE SAME

Polyimide having repeating units of the following formula (I) and its polyamic acid precursor having repeating units of the following formula (II) are disclosed; (where Y is a radical selected from the group consisting of a bond, divalent hydrocarbon having 1 to 10 carbons, hexafluorinated isopropyl...

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Hauptverfasser: SONOBE, YOSHIHO 2070, IIJIMAO, OIKAWA, HIDEAKI 2070, IIJIMAO, YAMAGUCHI, AKIHIRO 1-13-24, TAMAI, SHOJI 2070, IIJIMAO, OHTA, MASAHIRO 1541, YABEO, OHKOSHI, KOUJI 4-10-8, KAWASHIMA, SABURO 4-37-14, OYABE
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:Polyimide having repeating units of the following formula (I) and its polyamic acid precursor having repeating units of the following formula (II) are disclosed; (where Y is a radical selected from the group consisting of a bond, divalent hydrocarbon having 1 to 10 carbons, hexafluorinated isopropylidene, carbonyl, thio, sulfinyl, sulfonyl and oxide, and R is a tetra-valent radical selected from the group consisting of aliphatic radical having 2 and more carbons, cyclo-aliphatic radical, monoaromatic radical, condensed polyaromatic radical, and non-condensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function). Typical examples of polyimide and polyamic acid include where Y is thio radical and R is Y is a bond and R is III or IV, and Y is isopropylidene radical and R is IV. The polymers can be prepared from corresponding diamine and tetracarboxylic acid dianhydride. Polyimide or polyamic acid of this invention is excellent for high-temperature adhesive.