Process for removing transition metal ions from an aqueous solution with a reticular ion exchange resin containing a crystalline transition metal aluminate

Crystalline transition metal aluminates having to the formula MAv_aZv_b.nAl(OH)3.mH2O where M is a transition metal having a valence of +2 selected from Cu, Zn, Mn, Fe, Co, and Ni, where AZ represents negative valence ions or radicals, v is a valence of -1, -2, or -3, n is a value to provide a mol r...

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Bibliographische Detailangaben
Hauptverfasser:	LEE, JOHN MALCOLM, BAUMAN, WILLIAM CARREL
Format:	Patent
Sprache:	eng ; fre ; ger
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM,CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THERARE-EARTH METALS COMPOUNDS THEREOF FERROUS OR NON-FERROUS ALLOYS INORGANIC CHEMISTRY METALLURGY NON-METALLIC ELEMENTS ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRETREATMENT OF RAW MATERIALS PRODUCTION AND REFINING OF METALS THEIR RELEVANT APPARATUS TRANSPORTING TREATMENT OF ALLOYS OR NON-FERROUS METALS
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Beschreibung
Zusammenfassung:	Crystalline transition metal aluminates having to the formula MAv_aZv_b.nAl(OH)3.mH2O where M is a transition metal having a valence of +2 selected from Cu, Zn, Mn, Fe, Co, and Ni, where AZ represents negative valence ions or radicals, v is a valence of -1, -2, or -3, n is a value to provide a mol ratio of Al/M of at least 1/1, and m is an integer of from zero to the maximum for waters of hydration, with (va)+(vb) equal to 2, are prepared in alkaline aqueous medium wherein transition metal compounds to form adducts with amorphous hydrous alumina, Al(OH)3, said adducts forming crystals when heated, said aluminates being useful as ion exchangers and as spinel precursors.