Electrolytic initiation of polymerization in aqueous two-phase systems

An indirect process for electrolytically initiating the polymerization of ethylenically unsaturated monomer(s) comprises passing an electrical current through a two-phase system comprising:- (a) an organic phase, (b) a continuous aqueous phase capable of carrying an electric current, (c) a free radi...

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Bibliographische Detailangaben
Hauptverfasser:	GAYLOR, VERNA FRANCES, PICHLER, MARTY ANTON, BALL, LAWRENCE ERNEST
Format:	Patent
Sprache:	eng ; fre ; ger
Schlagworte:	CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP
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Beschreibung
Zusammenfassung:	An indirect process for electrolytically initiating the polymerization of ethylenically unsaturated monomer(s) comprises passing an electrical current through a two-phase system comprising:- (a) an organic phase, (b) a continuous aqueous phase capable of carrying an electric current, (c) a free radical source capable of forming a polymerization initiator, and (d) an electron transfer agent. The process exhibits high polymerization rates and yields.