PREPARATION OF FLUORINATED ACID FLUORIDES; PREPARATION OF ACIDS, AMIDES OR ESTERS DERIVED THEREFROM, COPOLYMERIZATION OF FLUORINATED VINYL ETHERS

ompounds represented by the general formulasare prepared by reacting halofluoropropylene oxides with fluorinated acid fluorides and ketones. These compounds may be decarboxylated to form useful monomers.whereina = 0 or an integer greater than 0;b = 0 or an integer greater than 0;c=O or 1;provided a...

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Bibliographische Detailangaben
Hauptverfasser: MOD, WILLIAM AUGUST, CARL, WILLIAM PAUL, EZZELL, BOBBY RAY
Format: Patent
Sprache:eng
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Zusammenfassung:ompounds represented by the general formulasare prepared by reacting halofluoropropylene oxides with fluorinated acid fluorides and ketones. These compounds may be decarboxylated to form useful monomers.whereina = 0 or an integer greater than 0;b = 0 or an integer greater than 0;c=O or 1;provided a + b + c = 0;n = zero or an integer greater than zero;Rf = F, perfluoroalkyl or fluorochloroalkyl;X = F, Cl, Br or mixtures thereof when n > 1;X' = Cl or Br;Y=Cl,Br,F or 1;Z = F, OH, NRR' or OA;R and R' are independently selected from the group consisting of hydrogen, an alkyl having one or more than one carbon atom and an aryl;A = alkali metal, quaternary ammonium, R or an aryl.These monomers may then be polymerized into polymers having useful properties.