METHOD OF OBTAINING HYDROCARBON BENZINE FRACTIONS FROM SINTHESIS-GAS

The invention relates to a method of obtaining Chydrocarbons by catalytic conversion of a synthesis gas. The synthesis gas containing H, CO and COand has volume ratio H/(CO+CO), equal 1-3, by contacting of gas at temperature 320-440°C and pressure 40-100 atm with bi-functional catalyst, which contai...

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Hauptverfasser: MYSOV VLADISLAV, MIKHAILOVICH, IONE KAZIMIRA, VLADIMIROVNA, STEPANOV VIKTOR, GEORGIEVICH
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IONE KAZIMIRA, VLADIMIROVNA
STEPANOV VIKTOR, GEORGIEVICH
description The invention relates to a method of obtaining Chydrocarbons by catalytic conversion of a synthesis gas. The synthesis gas containing H, CO and COand has volume ratio H/(CO+CO), equal 1-3, by contacting of gas at temperature 320-440°C and pressure 40-100 atm with bi-functional catalyst, which contains metaloxide component and zeolite with structure ZSM-5 or ZSM-11 and metaloxide component, containing iron from 0.3 to 1% wt. The process is carried out at circulation ratio preferably equal 4-30 and the synthesis gas diluted with methane and nitrogen up to 15% wt can be used as a feed stock. The inventive effect is aimed at increasing aromatic hydrocarbons content in benzine fractions and performing regeneration of bifunctional catalyst at temperatures not more than 430-440°C. Изобретение относится к способу получения Суглеводородов каталитической конверсией синтез-газа. Синтез-газ, содержащий CO, Hи COи имеющий объемное отношение Н/(СО+CO), равное 1-3, контактирует при температуре 320-440°С и давлении 40-100 атм с бифункциональным катализатором, содержащим металлоксидный компонент и цеолит со структурой ZSM-5 или ZSM-11, в состав которого входит железо в количестве от 0,3 до 1 мас.%. Процесс проводят при кратности циркуляции, предпочтительно равной 4-30, а в качестве сырья возможно использовать синтез-газ, разбавленный метаном и азотом до 15 об.%. Технический результат - повышение содержания ароматических углеводородов в бензиновой фракции и осуществление регенерации бифункционального катализатора при температуре, не превышающей 430-440°С.
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The synthesis gas containing H, CO and COand has volume ratio H/(CO+CO), equal 1-3, by contacting of gas at temperature 320-440°C and pressure 40-100 atm with bi-functional catalyst, which contains metaloxide component and zeolite with structure ZSM-5 or ZSM-11 and metaloxide component, containing iron from 0.3 to 1% wt. The process is carried out at circulation ratio preferably equal 4-30 and the synthesis gas diluted with methane and nitrogen up to 15% wt can be used as a feed stock. The inventive effect is aimed at increasing aromatic hydrocarbons content in benzine fractions and performing regeneration of bifunctional catalyst at temperatures not more than 430-440°C. Изобретение относится к способу получения Суглеводородов каталитической конверсией синтез-газа. 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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS
CRACKING HYDROCARBON OILS
FUELS
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
LUBRICANTS
METALLURGY
MINERAL WAXES
ORGANIC CHEMISTRY
PEAT
PETROLEUM, GAS OR COKE INDUSTRIES
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE
title METHOD OF OBTAINING HYDROCARBON BENZINE FRACTIONS FROM SINTHESIS-GAS
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