METHOD OF OBTAINING HYDROCARBON BENZINE FRACTIONS FROM SINTHESIS-GAS
The invention relates to a method of obtaining Chydrocarbons by catalytic conversion of a synthesis gas. The synthesis gas containing H, CO and COand has volume ratio H/(CO+CO), equal 1-3, by contacting of gas at temperature 320-440°C and pressure 40-100 atm with bi-functional catalyst, which contai...
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creator | MYSOV VLADISLAV, MIKHAILOVICH IONE KAZIMIRA, VLADIMIROVNA STEPANOV VIKTOR, GEORGIEVICH |
description | The invention relates to a method of obtaining Chydrocarbons by catalytic conversion of a synthesis gas. The synthesis gas containing H, CO and COand has volume ratio H/(CO+CO), equal 1-3, by contacting of gas at temperature 320-440°C and pressure 40-100 atm with bi-functional catalyst, which contains metaloxide component and zeolite with structure ZSM-5 or ZSM-11 and metaloxide component, containing iron from 0.3 to 1% wt. The process is carried out at circulation ratio preferably equal 4-30 and the synthesis gas diluted with methane and nitrogen up to 15% wt can be used as a feed stock. The inventive effect is aimed at increasing aromatic hydrocarbons content in benzine fractions and performing regeneration of bifunctional catalyst at temperatures not more than 430-440°C.
Изобретение относится к способу получения Суглеводородов каталитической конверсией синтез-газа. Синтез-газ, содержащий CO, Hи COи имеющий объемное отношение Н/(СО+CO), равное 1-3, контактирует при температуре 320-440°С и давлении 40-100 атм с бифункциональным катализатором, содержащим металлоксидный компонент и цеолит со структурой ZSM-5 или ZSM-11, в состав которого входит железо в количестве от 0,3 до 1 мас.%. Процесс проводят при кратности циркуляции, предпочтительно равной 4-30, а в качестве сырья возможно использовать синтез-газ, разбавленный метаном и азотом до 15 об.%. Технический результат - повышение содержания ароматических углеводородов в бензиновой фракции и осуществление регенерации бифункционального катализатора при температуре, не превышающей 430-440°С. |
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Изобретение относится к способу получения Суглеводородов каталитической конверсией синтез-газа. Синтез-газ, содержащий CO, Hи COи имеющий объемное отношение Н/(СО+CO), равное 1-3, контактирует при температуре 320-440°С и давлении 40-100 атм с бифункциональным катализатором, содержащим металлоксидный компонент и цеолит со структурой ZSM-5 или ZSM-11, в состав которого входит железо в количестве от 0,3 до 1 мас.%. Процесс проводят при кратности циркуляции, предпочтительно равной 4-30, а в качестве сырья возможно использовать синтез-газ, разбавленный метаном и азотом до 15 об.%. Технический результат - повышение содержания ароматических углеводородов в бензиновой фракции и осуществление регенерации бифункционального катализатора при температуре, не превышающей 430-440°С.</description><language>eng ; rus</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; CHEMISTRY ; CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS ; CRACKING HYDROCARBON OILS ; FUELS ; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC ; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS ; LUBRICANTS ; METALLURGY ; MINERAL WAXES ; ORGANIC CHEMISTRY ; PEAT ; PETROLEUM, GAS OR COKE INDUSTRIES ; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION ; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES ; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS ; REFORMING OF NAPHTHA ; TECHNICAL GASES CONTAINING CARBON MONOXIDE ; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS ; TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE</subject><creationdate>2010</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20101029&DB=EPODOC&CC=EA&NR=014326B1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25562,76317</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20101029&DB=EPODOC&CC=EA&NR=014326B1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>MYSOV VLADISLAV, MIKHAILOVICH</creatorcontrib><creatorcontrib>IONE KAZIMIRA, VLADIMIROVNA</creatorcontrib><creatorcontrib>STEPANOV VIKTOR, GEORGIEVICH</creatorcontrib><title>METHOD OF OBTAINING HYDROCARBON BENZINE FRACTIONS FROM SINTHESIS-GAS</title><description>The invention relates to a method of obtaining Chydrocarbons by catalytic conversion of a synthesis gas. The synthesis gas containing H, CO and COand has volume ratio H/(CO+CO), equal 1-3, by contacting of gas at temperature 320-440°C and pressure 40-100 atm with bi-functional catalyst, which contains metaloxide component and zeolite with structure ZSM-5 or ZSM-11 and metaloxide component, containing iron from 0.3 to 1% wt. The process is carried out at circulation ratio preferably equal 4-30 and the synthesis gas diluted with methane and nitrogen up to 15% wt can be used as a feed stock. The inventive effect is aimed at increasing aromatic hydrocarbons content in benzine fractions and performing regeneration of bifunctional catalyst at temperatures not more than 430-440°C.
Изобретение относится к способу получения Суглеводородов каталитической конверсией синтез-газа. Синтез-газ, содержащий CO, Hи COи имеющий объемное отношение Н/(СО+CO), равное 1-3, контактирует при температуре 320-440°С и давлении 40-100 атм с бифункциональным катализатором, содержащим металлоксидный компонент и цеолит со структурой ZSM-5 или ZSM-11, в состав которого входит железо в количестве от 0,3 до 1 мас.%. Процесс проводят при кратности циркуляции, предпочтительно равной 4-30, а в качестве сырья возможно использовать синтез-газ, разбавленный метаном и азотом до 15 об.%. Технический результат - повышение содержания ароматических углеводородов в бензиновой фракции и осуществление регенерации бифункционального катализатора при температуре, не превышающей 430-440°С.</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>CHEMISTRY</subject><subject>CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS</subject><subject>CRACKING HYDROCARBON OILS</subject><subject>FUELS</subject><subject>GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC</subject><subject>GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS</subject><subject>LUBRICANTS</subject><subject>METALLURGY</subject><subject>MINERAL WAXES</subject><subject>ORGANIC CHEMISTRY</subject><subject>PEAT</subject><subject>PETROLEUM, GAS OR COKE INDUSTRIES</subject><subject>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</subject><subject>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</subject><subject>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</subject><subject>REFORMING OF NAPHTHA</subject><subject>TECHNICAL GASES CONTAINING CARBON MONOXIDE</subject><subject>TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS</subject><subject>TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2010</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZHDxdQ3x8HdR8HdT8HcKcfT08_RzV_CIdAnyd3YMcvL3U3By9Yvy9HNVcAtydA7x9PcLBrL8fRWCPf1CPFyDPYN13R2DeRhY0xJzilN5oTQ3g7yba4izh25qQX58anFBYnJqXmpJvKujgaGJsZGZk6ExYRUAtwsq6w</recordid><startdate>20101029</startdate><enddate>20101029</enddate><creator>MYSOV VLADISLAV, MIKHAILOVICH</creator><creator>IONE KAZIMIRA, VLADIMIROVNA</creator><creator>STEPANOV VIKTOR, GEORGIEVICH</creator><scope>EVB</scope></search><sort><creationdate>20101029</creationdate><title>METHOD OF OBTAINING HYDROCARBON BENZINE FRACTIONS FROM SINTHESIS-GAS</title><author>MYSOV VLADISLAV, MIKHAILOVICH ; IONE KAZIMIRA, VLADIMIROVNA ; STEPANOV VIKTOR, GEORGIEVICH</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_EA014326B13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; rus</language><creationdate>2010</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>CHEMISTRY</topic><topic>CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS</topic><topic>CRACKING HYDROCARBON OILS</topic><topic>FUELS</topic><topic>GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC</topic><topic>GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS</topic><topic>LUBRICANTS</topic><topic>METALLURGY</topic><topic>MINERAL WAXES</topic><topic>ORGANIC CHEMISTRY</topic><topic>PEAT</topic><topic>PETROLEUM, GAS OR COKE INDUSTRIES</topic><topic>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</topic><topic>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</topic><topic>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</topic><topic>REFORMING OF NAPHTHA</topic><topic>TECHNICAL GASES CONTAINING CARBON MONOXIDE</topic><topic>TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS</topic><topic>TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE</topic><toplevel>online_resources</toplevel><creatorcontrib>MYSOV VLADISLAV, MIKHAILOVICH</creatorcontrib><creatorcontrib>IONE KAZIMIRA, VLADIMIROVNA</creatorcontrib><creatorcontrib>STEPANOV VIKTOR, GEORGIEVICH</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>MYSOV VLADISLAV, MIKHAILOVICH</au><au>IONE KAZIMIRA, VLADIMIROVNA</au><au>STEPANOV VIKTOR, GEORGIEVICH</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>METHOD OF OBTAINING HYDROCARBON BENZINE FRACTIONS FROM SINTHESIS-GAS</title><date>2010-10-29</date><risdate>2010</risdate><abstract>The invention relates to a method of obtaining Chydrocarbons by catalytic conversion of a synthesis gas. The synthesis gas containing H, CO and COand has volume ratio H/(CO+CO), equal 1-3, by contacting of gas at temperature 320-440°C and pressure 40-100 atm with bi-functional catalyst, which contains metaloxide component and zeolite with structure ZSM-5 or ZSM-11 and metaloxide component, containing iron from 0.3 to 1% wt. The process is carried out at circulation ratio preferably equal 4-30 and the synthesis gas diluted with methane and nitrogen up to 15% wt can be used as a feed stock. The inventive effect is aimed at increasing aromatic hydrocarbons content in benzine fractions and performing regeneration of bifunctional catalyst at temperatures not more than 430-440°C.
Изобретение относится к способу получения Суглеводородов каталитической конверсией синтез-газа. Синтез-газ, содержащий CO, Hи COи имеющий объемное отношение Н/(СО+CO), равное 1-3, контактирует при температуре 320-440°С и давлении 40-100 атм с бифункциональным катализатором, содержащим металлоксидный компонент и цеолит со структурой ZSM-5 или ZSM-11, в состав которого входит железо в количестве от 0,3 до 1 мас.%. Процесс проводят при кратности циркуляции, предпочтительно равной 4-30, а в качестве сырья возможно использовать синтез-газ, разбавленный метаном и азотом до 15 об.%. Технический результат - повышение содержания ароматических углеводородов в бензиновой фракции и осуществление регенерации бифункционального катализатора при температуре, не превышающей 430-440°С.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMISTRY CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS CRACKING HYDROCARBON OILS FUELS GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS LUBRICANTS METALLURGY MINERAL WAXES ORGANIC CHEMISTRY PEAT PETROLEUM, GAS OR COKE INDUSTRIES PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE |
title | METHOD OF OBTAINING HYDROCARBON BENZINE FRACTIONS FROM SINTHESIS-GAS |
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