Fremgangsmåde til minimering af racemiseringen ved fremstilling af optisk aktive [(aryloxy)-phenoxy]propionatherbicider
One of the routes to prepare optically active 2-(4-aryloxphenoxy)propionic acid ester herbicide is to couple optically active 2-(4-hydrophenoxy)propionic acid esters with halogenated aromatic or heteroaromatic compound. Conversion of the optically active 2-(4-hydroxyphenoxy)propionic acid ester into...
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Zusammenfassung: | One of the routes to prepare optically active 2-(4-aryloxphenoxy)propionic acid ester herbicide is to couple optically active 2-(4-hydrophenoxy)propionic acid esters with halogenated aromatic or heteroaromatic compound. Conversion of the optically active 2-(4-hydroxyphenoxy)propionic acid ester into the acid salt prior to the coupling step effectively prevents the racemization that unexpectedly occurs otherwise. |
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