Fungicid

New complex compounds are of the general formula (R1R2N.CS.S)k.X.(R3)n where X is an atom of cobalt, iron, manganese, nickel, zinc or a mixture of two of these metals corresponding to 1 atom, the atomic ratio of the metals being between 1: 10 and 10: 1 when X is a mixture of two metals; R1 is hydrog...

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Bibliographische Detailangaben
Hauptverfasser:	GERHARD ORTNER, FERDINAND GREWE
Format:	Patent
Sprache:	dan
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMISTRY COMPOSITIONS BASED THEREON HETEROCYCLIC COMPOUNDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
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Beschreibung
Zusammenfassung:	New complex compounds are of the general formula (R1R2N.CS.S)k.X.(R3)n where X is an atom of cobalt, iron, manganese, nickel, zinc or a mixture of two of these metals corresponding to 1 atom, the atomic ratio of the metals being between 1: 10 and 10: 1 when X is a mixture of two metals; R1 is hydrogen or an alkyl, cycloalkyl or aryl radical; R2 is hydrogen or an alkyl, cycloalkyl or aryl radical or -R4-NR5-CS-S; R4 is an alkylene radical of 1 to 6 carbon atoms; R5 is hydrogen, methyl or ethyl; k is 1 when R2 is -R4-NR5-CS-S-an 2 when R2 is hydrogen, alkyl, cycloalkyl or aryl; R3 is an unsaturated heterocyclic compound which may be substituted by one or more alkyl, cycloalkyl, aralkyl, aryl, mercapto or amino radicals; and n is 1, 2 or 3. They may be prepared by reacting a dithiocarbamic acid derivative of the formula (R1R2N.CS.S)kX, as defined in Claim 1, or an ammonia or amine complex thereof with an unsaturated mono- or polynuclear heterocyclic compound R3, as defined in Claim 1, if desired, in the presence of a solvent.ALSO:Pest control agents contain, in admixture with a solid or liquid diluent or carrier, a complex compound of the general formula (R1R2N. CS. S)k. X. (R3)n where X is an atom of cobalt, iron, manganese, nickel, zinc or a mixture of two of these metals corresponding to 1 atom, the atomic ratio of the metals being between 1 : 10 and 10 : 1 when X is a mixture of two metals; R1 is hydrogen or an alkyl, cycloalkyl or aryl radical; R2 is hydrogen or an alkyl, cycloalkyl or aryl radical or -R4-NR5-CS-S-; R4 is a C1-C6 alkylene radical; R5 is hydrogen, methyl or ethyl; k is 1 when R2 is R4-NR5-CS-S- and 2 when R2 is hydrogen, alkyl, cycloalkyl or aryl; R3 is an unsaturated heterocyclic compound which may be substituted by one or more alkyl, cycloalkyl, aralkyl, aryl, mercapto or amino radicals; and n is 1, 2 or 3. The complexes, which have especially good fungicidal activity, may be employed as an aqueous emulsion employing equal amounts of the complex, dimethyl formamide and a commercial non-ionic emulsifier.