Smidige og slagstærke sammensætninger på basis af polyvinylidenfluorid og fremgangsmåde til deres fremstilling
The invention concerns compositions based on flexible and resilient poly(vinylidene fluoride), comprising for 100 parts by weight of a vinylidene fluoride (VF2) homopolymer (A) or a VF2 copolymer (A) and at least another monomer copolymerisable with VF2, wherein for 100 parts by weight of VF2 said m...
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Zusammenfassung: | The invention concerns compositions based on flexible and resilient poly(vinylidene fluoride), comprising for 100 parts by weight of a vinylidene fluoride (VF2) homopolymer (A) or a VF2 copolymer (A) and at least another monomer copolymerisable with VF2, wherein for 100 parts by weight of VF2 said monomer is present in an amount ranging between 0 and 30 parts by weight, 0.5 to 10 parts by weight of an elastomer B and 0.5 to 10 parts of a plasticizer C, with the additional condition that the sum of B plus C is from 1 to 10.5 parts by weight and, that the vinylidene fluoride homopolymer A is selected such that it has a flow index, measured according to the ISO 1133 standard, at 230 DEG C under a load of 5 kg, less than 5g/10 min and a critical modulus GC, measured at 190 DEG C, at the intersection of shearing moduli in molten state G' and G", ranging between 5 and 22 kPa. Generally, said compositions are suitable for producing objects, articles such as films, tube sheaths, pipes and the like subjected to stresses in high and/or low temperatures, in contact with particularly aggressive substances (such as hydrocarbons, strong acids, solvents, mineral or organic bases) where their resistance and flexibility are particularly required ( oil and gas industry, chemical engineering, building industry and public works). |
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