Loesungsmittel-Extraktionsverfahren zum Trennen eines Gemisches organischer Verbindungen

An organic mixture containing a hydrocarbon is subjected to a solvent extraction process in which a sulfolane (i.e. cyclic tetramethylene sulphone or a substitution derivative thereof) or a 2-sulfolene or a mixture of both is employed as the solvent. The solvent chosen is one which is liquid and stable at the temperature at which the process is carried out and to which the organic mixture is inert and the process is one in which the organic mixture is subjected to liquid-liquid contact or liquid-vapour contact with the solvent to produce two phases which are then separated. The process may, if desired, be one of extractive distillation. The sulfolanes and 2-sulfolenes listed include not only hydrocarbon-substituted derivatives but also derivatives containing polar groupings having oxygen, nitrogen, sulphur or halogen in the grouping. Auxiliary solvents and anti-solvents which may be used in conjunction with the sulfolanes or 2-sulfolenes are mentioned. Examples of mixtures which may be separated by the process are hydrocarbon mixtures such as gasoline distillates containing benzene, toluene, xylenes, ethyl benzene, mesitylene and cumene; naphthenes and paraffins; gasolines, kerosines, fuel oils and lubricating oils. Other organic mixtures containing hydrocarbons which may be subjected to solvent extraction are those produced in various chemical industrial processes of the coal, lignite and petroleum industries, such as mixtures of nitrogen bases and petroleum; non-cellulosic wood by-products containing hydrocarbons such as pyroligneous acid, light oils, heavy oils, tar oils, black liquors from the sulphate process and soda process, brown oil from the sulphite process and tall oil. Apparatus is described for carrying out the solvent extraction process. In the examples, solvent extraction processes are described in which (1) mineral lubricating oil is freed from sulphur-containing and low viscosity impurities with the aid of 3-methyl sulfolane or 2,4-dimethyl sulfolane; (2) petroleum distillate is freed from mercaptans with the aid of 2,4-dimethyl sulfolane, ethyl-3-sulfolaryl sulphide or 2,4-dimethyl-4-sulfolane; and (3) tall oil is freed from dark colouring matter with the aid of dimethyl sulfolene and hot acid octanes. U.S.A. Specification 2,246,257 is referred to. The Specification as open to inspection under Sect. 91 refers to the general application of the solvent extraction process to any organic mixture and numerous organic mixtures which do not cont