PROPYLENCOPOLYMER UND VERFAHREN ZU DESSEN HERSTELLUNG

Disclosed are propylene copolymers produced by the aid of a specific metallocene catalyst system, wherein a percentage of mis-insertion in the copolymer is highly controlled and the copolymers possess heat-resisting property and a high melt strength and a low MFR and are narrow in molecular weight d...

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Bibliographische Detailangaben
Hauptverfasser: OHGI, YOSHIYUKI, YASUDA, YOSHITOYO, SAITO, JUN, FUJITA, HIROYUKI, TSUTSUI, MOTOTAKE, USHIODA, TSUTOMU
Format: Patent
Sprache:ger
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Zusammenfassung:Disclosed are propylene copolymers produced by the aid of a specific metallocene catalyst system, wherein a percentage of mis-insertion in the copolymer is highly controlled and the copolymers possess heat-resisting property and a high melt strength and a low MFR and are narrow in molecular weight distribution excellent in particulate properties as well as a process for producing the copolymers possessing high steroregularity at a practical polymerization temperature. The gist of the present invention resides in production of propylene copolymers wherein copolymerization* with alpha , omega -diene is carried out by the aid of a supported-type catalyst system comprised predominantly of the following compound (A), (B), (C) and (D) at a temperature above 45 DEG C: the compound (A): a specific metallocene compound represented by Q (C5H4-mR m) (C5H4-nR n) MXY, the compound (B): an aluminoxane, the compound (C): an organoaluminum compound, and the compound (D): a particulate carrier. An important feature of the propylene copolymers of the present invention resides in the fact that the copolymers are highly stereoregular and have a ratio of a mis-inserted unit based on 2,1-insertion of propylene monomer in the total propylene insertion being defined within a specific range.