Verfahren zur Herstellung von Poly (arylcarbonat)en
A process for the preparation of poly(arylcarbonate)s, comprising reaction of dialkyl carbonates with bisphenols in the presence of selected distannoxane compounds in a first step to obtain an oligo(arylcarbonate). The oligomer is then polycondensed in a second step, either by itself or with dipheny...
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Zusammenfassung: | A process for the preparation of poly(arylcarbonate)s, comprising reaction of dialkyl carbonates with bisphenols in the presence of selected distannoxane compounds in a first step to obtain an oligo(arylcarbonate). The oligomer is then polycondensed in a second step, either by itself or with diphenyl carbonate, using an organo-tin or -titanium catalyst. The process yields aromatic polycarbonates that are characteristically free of color and gel. |
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