Isomerisierung von C8-Aromaten mit Hilfe eines Katalysators der ein modifiziertes, aus Silico-alumino-phosphat aufgebautes Molekularsieb, enthält

A non-equilibrium C8 aromatic-feed mixture is selectively isomerized to obtain an isomerized product enriched in para-xylene by contacting the feed in the presence of hydrogen with a catalyst containing a combination of a platinum group component with an SM-3 acidic crystalline silicaaluminophosphat...

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Hauptverfasser: PATTON, ROBERT L, LESCH, DAVID A, HAMMERMAN, JOHN I, REYNOLDS, THOMAS M, HOLMGREN, JENIFFER S, ROESELER, CARA MOY, FLANIGEN, EDITH M, GAJDA, GREGORY J
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Sprache:ger
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Zusammenfassung:A non-equilibrium C8 aromatic-feed mixture is selectively isomerized to obtain an isomerized product enriched in para-xylene by contacting the feed in the presence of hydrogen with a catalyst containing a combination of a platinum group component with an SM-3 acidic crystalline silicaaluminophosphate molecular sieve at C8 aromatic isomerization conditions. The SM-3 molecular sieve is enriched in framework silicon at the surface, resulting in a greater yield of para-xylene compared to prior art processes.