Verfahren zum Abbruch einer Emulsionspolymerisation

A process for shortstopping a free radical polymerization of a conjugated diene and optionally a vinyl-substituted aromatic in an aqueous emulsion, using a hydroperoxide as initiator and a redox activator, comprising a divalent transition metal, a reducing agent and optionally being carried out in t...

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Hauptverfasser: WILLEMSEN, JOHANNES ARNOLDUS MARIA, NL-3196 KK ROTTERDAM/PERNIS, NL, DE VRIES, SIJTSKE MINNIE, NL-3196 KK ROTTERDAM/PERNIS, NL
Format: Patent
Sprache:ger
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Zusammenfassung:A process for shortstopping a free radical polymerization of a conjugated diene and optionally a vinyl-substituted aromatic in an aqueous emulsion, using a hydroperoxide as initiator and a redox activator, comprising a divalent transition metal, a reducing agent and optionally being carried out in the presence of a modifier, and being performed by using as sole shortstopping agent an alkali metal polysulphide, and polymeric products obtained therewith.