Wässrige autooxydierbare Überzugszusammensetzung

A water-based autoxidisable coating composition, especially a gloss or partial gloss coating composition (eg paint, varnish, woodstain or timber preservative) suitable for application at ambient temperatures which comprises water, minimal organic cosolvent and a partially esterified carboxylic acid...

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Bibliographische Detailangaben
Hauptverfasser: TAYLOR, PHILIP LOUIS, BURNHAM, BUCKINGSHAMSHIRE SL1 7LT, GB, NICKS, PETER FRANCIS, MAIDENHEAD SL6 7UE, GB, GOSLING, JULIAN JOHN, BURNHAM, SLOUGH, BERKSHIRE SL1 6JD, GB, BROMLEY, CHARLES WILLIAM ALFRED, BOURNE END, BUCKINGHAMSHIRE SL8 5HB/GB, GB
Format: Patent
Sprache:ger
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Beschreibung
Zusammenfassung:A water-based autoxidisable coating composition, especially a gloss or partial gloss coating composition (eg paint, varnish, woodstain or timber preservative) suitable for application at ambient temperatures which comprises water, minimal organic cosolvent and a partially esterified carboxylic acid film-forming copolymer at least partially neutralised by monovalent cations wherein the copolymer contains added 3-allyloxy-2-hydroxypropyl groups or certain analogues derived from addition of allyl glycidyl ether or certain of its analogues to carboxylic acid groups, in a copolymeric backbone portion derivable from a prepolymer of weight average molecular weight less than 30 000. The partially esterified copolymer has an acid value of 25 to 60 and preferably a dynamic solution viscosity of 1 to 500 Pa.sec measured in 1-methoxy-2-hydroxy propane by oscillatory parallel plate rheometer. The coatings lap well, dry quickly and achieve acceptable water resistance. Also the optionally unneutralised copolymer and the coating composition when containing a minor amount of particulate copolymer which is found to improve gloss. Discolouration on ageing may be improved by neutralising with Group 1 metal cations.