Olefin polymerisation catalyst esp. for direct isotactic/elastomer polypropylene@ prodn

A novel olefin polymerisation catalyst comprises: (A) a sub-Gp. III, IV, V or VI metallocene; (B) aluminoxane; (C) a Gp. II, III or IV metal oxide; and (D) an organometallic cpd. of formula (I). Claimed prepn. is by mixing (A) and (B) and then mixing the prod. with a (C)/(D) reaction prod. MR1R2R3R4...

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Hauptverfasser: NEISL, WOLFGANG. DR., LICHTENBERG, AT, ERNST, EBERHARD.NAT.HABIL., KATSDORF, AT, REUSNER, JENS.NAT., TRAUN, AT
Format: Patent
Sprache:eng ; ger
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Zusammenfassung:A novel olefin polymerisation catalyst comprises: (A) a sub-Gp. III, IV, V or VI metallocene; (B) aluminoxane; (C) a Gp. II, III or IV metal oxide; and (D) an organometallic cpd. of formula (I). Claimed prepn. is by mixing (A) and (B) and then mixing the prod. with a (C)/(D) reaction prod. MR1R2R3R4 (I) M = sub-Gp. III, IV, V or VI transition metal; and R1-R4 = allyl, benzyl, neophyl or neopentyl.