Gemische isomerer Pentansäuren, aus ihnen hergestellte Ester und deren Verwendung als Schmiermittel

Isomeric mixtures of pentanoic acids are prepared by subjecting butene-1/butene-2 mixtures to hydroformylation to form aldehyde mixtures, followed by oxidation of the aldehyde mixtures which have been separated off from the reaction product. The hydroformylation is carried out in a heterogeneous sys...

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Hauptverfasser:	WEBER, JUERGEN., 46147 OBERHAUSEN, DE, SPRINGER, HELMUT, 46145 OBERHAUSEN, DE, KALBFELL, HEINZ, 46514 SCHERMBECK, DE, DAEMBKES, GEORG., 46537 DINSLAKEN, DE, GREB, WOLFGANG., 46535 DINSLAKEN, DE, WIEBUS, ERNST, 46147 OBERHAUSEN, DE, FROHNING, CARL-DIETER., 45265 WESEL, DE, KAPPESSER, HARALD, 46149 OBERHAUSEN, DE, BAHRMANN, HELMUT., 46499 HAMMINKELN, DE, LAPPE, PETER., 46539 DINSLAKEN, DE, MUELMANN, EBERHARD VON, 46147 OBERHAUSEN, DE, HEYMANNS, PETER., 54147 ESSEN, DE
Format:	Patent
Sprache:	ger
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY FUELS GENERAL METHODS OF ORGANIC CHEMISTRY INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATINGCOMPOSITIONS LUBRICANTS LUBRICATING COMPOSITIONS METALLURGY ORGANIC CHEMISTRY PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATINGINGREDIENTS IN A LUBRICATING COMPOSITION
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Zusammenfassung:	Isomeric mixtures of pentanoic acids are prepared by subjecting butene-1/butene-2 mixtures to hydroformylation to form aldehyde mixtures, followed by oxidation of the aldehyde mixtures which have been separated off from the reaction product. The hydroformylation is carried out in a heterogeneous system in the presence of rhodium catalysts which are dissolved in water. The mixture of isomeric 5 carbon monocarboxylic acids produced, when esterified with polyhydric alcohols, yields mixtures of isomeric esters which are useful as lubricants for refrigerant compressors operated with chlorine-free, at least partly fluorinated hydrocarbons as the refrigerant.