Herstellung von Poly(Vinylaminen) mit hohem Molekulargewicht

The inverse emulsion polymerization of a monomer of the formula wherein R and R represent hydrogen or a C1-C4 alkyl group, using a surfactant system having a hydrophilic-lipophilic balance value from 4 to 9, an azo-type free radical initiator and certain hydrocarbon liquids to yield a water-in-oil e...

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Bibliographische Detailangaben
Hauptverfasser:	VIJAYENDRAN, BHEEMA RAO, EMMAUS, PA 18049, US, LAI, TA-WANG, MACUNGIE, PA 18062, US
Format:	Patent
Sprache:	ger
Schlagworte:	ADHESIVES CHEMISTRY COMPOSITIONS BASED THEREON DYES EARTH DRILLING EARTH DRILLING, e.g. DEEP DRILLING FIXED CONSTRUCTIONS IMPREGNATING OR COATING OF PAPER MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE METALLURGY MINING MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR ASLURRY OF MINERALS FROM WELLS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PAPER NOT OTHERWISE PROVIDED FOR PAPER-MAKING POLISHES PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D PRODUCTION OF CELLULOSE PULP COMPOSITIONS TEXTILES THEIR PREPARATION OR CHEMICAL WORKING-UP TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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Beschreibung
Zusammenfassung:	The inverse emulsion polymerization of a monomer of the formula wherein R and R represent hydrogen or a C1-C4 alkyl group, using a surfactant system having a hydrophilic-lipophilic balance value from 4 to 9, an azo-type free radical initiator and certain hydrocarbon liquids to yield a water-in-oil emulsion of a homopolymer of at least 10 average molecular weight, the emulsion having a viscosity less than 10 cps, at 15% solids, 60 rpm Brookfield and 20 DEG C. Also disclosed is the preparation of poly(vinylamines) of at least 10 average molecular weight by acid or base hydrolysis of the homopolymer emulsion. Also disclosed are drilling mud compositions, cements for drilling holes, completion fluids, acidized fracturing fluids, and wet-end paper additives containing the poly(vinylamines) and demonstrating superior properties.