VERFAHREN ZUR HERSTELLUNG VON PENTENSAEUREALKYLESTERN

Alkyl pentenoates are prepared by reacting butadiene with carbon monoxide and an alkanol in the presence of a cobalt carbonyl complex and a tertiary, aromatic heterocyclic nitrogen base at from 80 DEG to 160 DEG C. under from 100 to 1,000 bar in the presence of from 0.1 to 10% by volume of hydrogen,...

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Hauptverfasser: PANITZ,PAUL, SCHUCH,GUNTER,DR, KUEHN,GEBHARD, BERTLEFF,WERNER,DR, JOERG,WILFINGER,HANS, MAERKL,ROBERT,DR, HARDER,WOLFGANG,DR
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Sprache:ger
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Zusammenfassung:Alkyl pentenoates are prepared by reacting butadiene with carbon monoxide and an alkanol in the presence of a cobalt carbonyl complex and a tertiary, aromatic heterocyclic nitrogen base at from 80 DEG to 160 DEG C. under from 100 to 1,000 bar in the presence of from 0.1 to 10% by volume of hydrogen, based on the amount of carbon monoxide used.