Method and device for removing metal ions from aqueous solutions containing them

In the method, the metal ions are electrolytically converted, in at least one electrolysis cell, to an oxidation stage in which they form anionic complexes, one or more cationic surfactants are added to the solution, and the precipitates formed in this process are floated with the aid of a gas and t...

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Hauptverfasser: RIEGER,CHRISTINE, KROEBEL,REINHARD,DR, HECKMANN,KLAUS,DR
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KROEBEL,REINHARD,DR
HECKMANN,KLAUS,DR
description In the method, the metal ions are electrolytically converted, in at least one electrolysis cell, to an oxidation stage in which they form anionic complexes, one or more cationic surfactants are added to the solution, and the precipitates formed in this process are floated with the aid of a gas and thereby removed from the solution. The object of the invention is to avoid, with less effort than in the case of the methods belonging to the prior art, interfering chemical reactions, such as reoxidation of metal ions etc., to ensure complete complexing and precipitation and to render any use of chemical correction reactions superfluous. This is achieved by causing a flotation gas to be evolved, continuously or discontinuously, simultaneously at least at one of the electrodes and by establishing the oxidation stage necessary for the precipitation of at least one of the metal-ion components at least at one of the electrodes.
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The object of the invention is to avoid, with less effort than in the case of the methods belonging to the prior art, interfering chemical reactions, such as reoxidation of metal ions etc., to ensure complete complexing and precipitation and to render any use of chemical correction reactions superfluous. 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The object of the invention is to avoid, with less effort than in the case of the methods belonging to the prior art, interfering chemical reactions, such as reoxidation of metal ions etc., to ensure complete complexing and precipitation and to render any use of chemical correction reactions superfluous. 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language eng ; ger
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subjects APPARATUS THEREFOR
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM,CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THERARE-EARTH METALS
DIFFERENTIAL SEDIMENTATION
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS
FLOTATION
INORGANIC CHEMISTRY
MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLIDMATERIALS OR FLUIDS
METALLURGY
PERFORMING OPERATIONS
SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATICTABLES OR JIGS
TRANSPORTING
TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
title Method and device for removing metal ions from aqueous solutions containing them
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