Organosilicon-modified polydienes, process for their preparation, and their use as demulsifiers for crude oil

Organosilicon-modified polydienes of the formula in which Z are chain-terminating groups, R is hydrogen or methyl, R , R and R are lower alkyl having 1 to 4 carbon atoms, which may be identical or different within the polymeric molecule, R is methyl or [O-(R O-)3-R ], R , R and R are alkylene having...

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Hauptverfasser: KOERNER,GOETZ,DR, WEITEMEYER,CHRISTIAN,DR
Format: Patent
Sprache:eng ; ger
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Zusammenfassung:Organosilicon-modified polydienes of the formula in which Z are chain-terminating groups, R is hydrogen or methyl, R , R and R are lower alkyl having 1 to 4 carbon atoms, which may be identical or different within the polymeric molecule, R is methyl or [O-(R O-)3-R ], R , R and R are alkylene having 2 to 4 carbon atoms, the C:O ratio is from 2.25 to 3:1 in R O, from 3 to 2.75:1 in R O and from 2 to 3:1 in R O, but the difference between the C:O ratios in R O and R O must be >/= 0.25, and the C:O ratio in R O must be < that in R O or > that in R O, a is from 0 to 2, 0 < b < 3, where 0 < a + b < 3, p, q and s are >/= 2, x and y are >/= 0, z is >/= 3. The invention furthermore relates to processes for the preparation of these compounds, and the use thereof as demulsifiers for crude oil/water emulsions.