VERFAHREN ZUR HERSTELLUNG VON UNGESAETTIGTEN POLYESTERHARZEN

In the prodn. of unsatd. polyester resins by polycondens. of the 2-naphthol-diene adduct (I) with maleic anhydride (IA) and dicarboxylic acid or their anhydrides with glycol and then copolymerisation with a crosslinking monomer, unsatd. polyester obtd. in known manner is first modified with diisocya...

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Hauptverfasser: JEDLINSKI,ZBIGNIEW,DR...,GLEIWITZ, THOMALLA,BOGDAN,DR, JACH,JAN, KUBICA,STEFAN, JEDLINSKI,STANISLAW, PILAT,WLADYSLAW
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Sprache:ger
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Zusammenfassung:In the prodn. of unsatd. polyester resins by polycondens. of the 2-naphthol-diene adduct (I) with maleic anhydride (IA) and dicarboxylic acid or their anhydrides with glycol and then copolymerisation with a crosslinking monomer, unsatd. polyester obtd. in known manner is first modified with diisocyanate (II) and then crosslinked. Pref. (II) is an aliphatic diisocyanate of formula OCN-(CH2)n-NCO (with n = 2-10) or aromatic diisocyanate, e.g. 2,4-IDI and its isomers. (II) is added in an amt. of 0.5-5 wt.% w.r.t. the unsatd. polyester. Pref. a soln. of half the amt. of unsatd. polyester in styrene is treated with (II) and then the other half is added. The resin has increased chemical and thermal stability and good industrial properties.