VERFAHREN ZUR HERSTELLUNG PERHALOGENIERTER DIARYLCARBONATE

1. Process for the preparation of perhalogenated diaryl carbonates by reacting phosgene with an alkali metal salt of a perhalogenated phenol in an intensively mixed two-phase mixture of an aqueous alkali metal salt solution of the perhalogenated phenol and a water-immiscible organic solvent, charact...

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Hauptverfasser: MARGOTTE,DIETER,.DR, ALEWELT,WOLFGANG,.DR, VERNALEKEN,HUGO,.DR
Format: Patent
Sprache:ger
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Zusammenfassung:1. Process for the preparation of perhalogenated diaryl carbonates by reacting phosgene with an alkali metal salt of a perhalogenated phenol in an intensively mixed two-phase mixture of an aqueous alkali metal salt solution of the perhalogenated phenol and a water-immiscible organic solvent, characterized in that a solvent is used in which the chloroformic acid perhalogen phenyl ester forming as the intermediate product remains dissolved and the perhalogenated diaryl carbonate is insoluble and a tertiary amine or a quaternary ammonium compound is used as catalyst.