VERFAHREN ZUR HERSTELLUNG PERHALOGENIERTER DIARYLCARBONATE
1. Process for the preparation of perhalogenated diaryl carbonates by reacting phosgene with an alkali metal salt of a perhalogenated phenol in an intensively mixed two-phase mixture of an aqueous alkali metal salt solution of the perhalogenated phenol and a water-immiscible organic solvent, charact...
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Zusammenfassung: | 1. Process for the preparation of perhalogenated diaryl carbonates by reacting phosgene with an alkali metal salt of a perhalogenated phenol in an intensively mixed two-phase mixture of an aqueous alkali metal salt solution of the perhalogenated phenol and a water-immiscible organic solvent, characterized in that a solvent is used in which the chloroformic acid perhalogen phenyl ester forming as the intermediate product remains dissolved and the perhalogenated diaryl carbonate is insoluble and a tertiary amine or a quaternary ammonium compound is used as catalyst. |
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