Pyrazolium betaine cpds. and their prepn. - from beta:en:hydrazino-carboxylic acid derivs. and acid chloride, useful as growth inhibitor
New pyrazolium betaines (I) have formula: (in which R' is an opt. phenyl-substd. linear or branched alkyl gp.; R2 is -OR 5 or -NR6R7; R5 is as R1; R6 and R7 are h, the same as R1 or aryl; Ro and R4 are (un)branched alkyl, which can be connected in a 5-7 membered ring, opt. contg. O os S). (I) a...
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Zusammenfassung: | New pyrazolium betaines (I) have formula: (in which R' is an opt. phenyl-substd. linear or branched alkyl gp.; R2 is -OR 5 or -NR6R7; R5 is as R1; R6 and R7 are h, the same as R1 or aryl; Ro and R4 are (un)branched alkyl, which can be connected in a 5-7 membered ring, opt. contg. O os S). (I) are useful as growth inhibitors. They are prepd. by reacting beta-enhydrazinocarboxylic acid derivs. of formula R3R4N-NH-CR1=CH-CO-R2 with an acid chloride of formula R8-CO-Cl (in which R8 is Cl or -O-C6H4R9; R9 is H, (un)branched alkyl or halo) at 0-150 degrees C in an aprotic solvent in the presence of a tert. amine. |
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