Catalysed oligomerisation of ethylene - using catalysts contg. metallic aluminium and nickel acetyl acetonate in satd. hydrocarbons

Ethylene oligomers are prepd. by the oligomerisation of ethylene in satd. hydrocarbons at 80-250 degrees C, pref. 150-200 degrees C, and at 35-250 kp/cm2 press., in the presence of a catalyst comprising the reaction prod. of metallic Al with an incompletely chlorinated satd. by hydrocarbon and nicke...

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Hauptverfasser:	OGLY KULJEV,TOFIK MUSTAFA, ALEKSANDROVITSCH DALIN,MARK, OGLY KJASIMOV,SABIR MAMEDALI, OGLY SEIDOV,NADYR MIR-IBRAGIM
Format:	Patent
Sprache:	eng ; ger
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE THEIR RELEVANT APPARATUS TRANSPORTING
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Zusammenfassung:	Ethylene oligomers are prepd. by the oligomerisation of ethylene in satd. hydrocarbons at 80-250 degrees C, pref. 150-200 degrees C, and at 35-250 kp/cm2 press., in the presence of a catalyst comprising the reaction prod. of metallic Al with an incompletely chlorinated satd. by hydrocarbon and nickel acetyl acetonate in a wt. ratio of 1:0.1-10:0.007-0.1, pref. 1:0.4-50:0.01-0.03, in satd. hydrocarbons. Catalyst components are storage-stable and easily tran transportable. The oligomers have an ave. mol. wt. of 30-300 and are suitable in the prepn. of detergents, hydroxy-alcohols, motor oil and lubricants. The oligomers are obtd. in high yields in opt. continuous processes.