Thickener for aq. polymer dispersions - which is self cross linking, stable, weakly cationic condensate of ammonia with polyether chlorohydrin
In parent patent, weakly cationic condensates (I) of NH3 with polyether chlorhydrin cpds. (II) are prepd. by reacting an aq. or alcoholic NH3 soln. with (II) of formula (III): R -O(-A-O)n- CH2-CH(CH2Cl)-O mCH2-CH(CH2Cl)OH p, (III), or the polyepoxide derived from this by elimination of HCl in an NH3...
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Zusammenfassung: | In parent patent, weakly cationic condensates (I) of NH3 with polyether chlorhydrin cpds. (II) are prepd. by reacting an aq. or alcoholic NH3 soln. with (II) of formula (III): R -O(-A-O)n- CH2-CH(CH2Cl)-O mCH2-CH(CH2Cl)OH p, (III), or the polyepoxide derived from this by elimination of HCl in an NH3 (100%):(II) wt. ratio of 1:15-80. R is a 2-8C (cyclo)aliphatic p-valent gp. A is -CH2CH2- and/or -CH2-CHMe-. n = 4-30, m = 0-4, p = 0-6. (I) has a viscosity of min. 50 cP at pH 7 in 20% aq. soln. at 20 degrees C. In the addition, (I) is used as thickener for aq. polymer dispersions in an amt. of 0.1-10 wt.% w.r.t. the solids content of the dispersion. They are used in paper staining colours, various compsns. used for treating textiles, e.g. for the prodn. of artificial leather, leather-like coatings and back coatings, and in paints and printing pastes. |
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