VERFAHREN ZUR ENTSCHWEFELUNG SCHWERMETALLHALTIGER RUECKSTANDSOELE

The hydrodesulphurisation (HDS) of residua contg. >100 ppm. of heavy metals (Ni and V) and >3 wt% asphalt is carried out on a fixed bed of an extruded catalyst comprising a combination of Group V and VIII metal cpds. and Al2O3, the catalyst having a pore distribution such that 40-70% of the to...

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Hauptverfasser:	PRINTZ,DIETMAR, BAETZ,ROBERT,DR, STOECKER,HANS, STUMPF,ROLAND, ONDERKA,ERIKA, NETTE,WOLFGANG,DR, RISSE,GERHARD, BECKER,KARL,DR, PFEIFFER,FRITZ,DR, GROSSMANN,MANFRED,DR, BLUME,HERMANN,DR, MUELLER,DIETER, JOHN,HEINO,DR
Format:	Patent
Sprache:	ger
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CRACKING HYDROCARBON OILS FUELS LUBRICANTS METALLURGY MINERAL WAXES PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING
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Zusammenfassung:	The hydrodesulphurisation (HDS) of residua contg. >100 ppm. of heavy metals (Ni and V) and >3 wt% asphalt is carried out on a fixed bed of an extruded catalyst comprising a combination of Group V and VIII metal cpds. and Al2O3, the catalyst having a pore distribution such that 40-70% of the total pore vol. is in pores with a dia. of =300A degrees, =10% is in pores with a dia. of 300-3000A degrees, and 30-60% is in pores with a dia. of 3000-50,000A degrees. Heavy metal deposition on the catalysts is reduced from 50-70% (for conventional catalysts) to 20-50% of the amt. present in the oil, thus increasing the life of the catalyst.