DE2350765
1435067 Films and laminates by sintering BAYER AG 8 Oct 1974 [10 Oct 1973] 43504/74 Headings B5B and B5N [Also in Division B2] Films and laminates are formed by laying polyurethane and/or polyurethane urea on a flexible temporary support for stripping therefrom or coating a flexible permanent suppor...
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Zusammenfassung: | 1435067 Films and laminates by sintering BAYER AG 8 Oct 1974 [10 Oct 1973] 43504/74 Headings B5B and B5N [Also in Division B2] Films and laminates are formed by laying polyurethane and/or polyurethane urea on a flexible temporary support for stripping therefrom or coating a flexible permanent support by (A), applying to the support a dry polyurethane and/or polyurethane urea powder which: (a) comprises smooth, spheroidal particles; (b) has an average diameter of 5 to 200 Á; (c) has an ionic group content of 1 to 15, milliequivalents per 100 g.; (d) has an electrical resistance of 1010 to 1014 ohm./cm.; (e) has an intrinsic melt index (I.M.I.) curve (ASTM D1238-65T) in the shape of the ascending branch of a parabola such that the I.M.I. changes within a temperature interval of from 5 to 50 C. from 2 g. per 10 minutes to 50 g. per 10 minutes, and (B) sintering or fusing the powder by heat. The powder may contain Mg stearate as lubicant and C black, TiO 2 , aluminium bronze, iron pigment or cadmium pigment. Separate pigments may be used in several powders each issuing from one coating nozzle to form a multicolour film. Suitable methods of preparing the polymers are listed. The powder is preferably applied by doctor spreading and may be heated just to its melting point to produce a macroporous layer or above to produce a continuous film. In examples various two layer films are produced, one of which may be macroporous, the layers being the same or of different polyurethanes. In Examples (3) a one- or two-layer film is wet laminated to one or both sides of cotton fabric, polyester fabric or a non-woven fibre web using polyurethane solution or dispersion as adhesive, (7) a knitted cotton fabric is laminated to a two-layer film without adhesive while the film is tacky, (9) a two-layer film is laminated to a polyester/polyamide non-woven fibre web, and (10) a cotton/poplin fabric is calendered to a one-layer film. |
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