TEILCHENFOERMIGES POLYMERMATERIAL MIT SPEZIELLEN FORMEIGENSCHAFTEN

1451891 Moulding of graft polymers DEFENCE SECRETARY OF STATE FOR 19 Sept 1973 [25 Sept 1972] 44136/72 Heading C3G A moulding is produced from particulate polymer material in which the particles have a nucleus of thermoplastic polymer material surrounded by a cross-linked polymer layer and an outer...

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Hauptverfasser: JOHN FYDELOR,PETER, BRIAN PITHOUSE,KENNETH
Format: Patent
Sprache:ger
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Zusammenfassung:1451891 Moulding of graft polymers DEFENCE SECRETARY OF STATE FOR 19 Sept 1973 [25 Sept 1972] 44136/72 Heading C3G A moulding is produced from particulate polymer material in which the particles have a nucleus of thermoplastic polymer material surrounded by a cross-linked polymer layer and an outer polar graft copolymer layer, the said moulding having the property that when it is heated to a determinable temperature below the temperature at which it softens the particles separate with respect to their nearest neighbours such that the material disintegrates to its original particulate form. The thermoplastic polymer forming the nuclei of the particles may be polyethylene, polypropylene, polytetrafluoroethylene, partially fluorinated polyolefin, partially chlorinated polyolefin or nylon and the monomer used to form the outer graft polymer layer and optionally also to act as cross-linking agent in the cross-linked polymer layer may be an ethylenically unsaturated carboxylic acid, acrylamide or methacrylamide. Examples are given in which polyethylene powder or polytetrafluoroethylene fluff is subjected to irradiation from a Co60 source in an aqueous solution of acrylic acid and the resulting graft polymer powder is converted to its potassium salt form and moulded.