VERFAHREN ZUR HERSTELLUNG VON GERADKETTIGEN PRIMAEREN ALKOHOLEN

VERFAHREN ZUR HERSTELLUNG VON GERADKETTIGEN PRIMAEREN ALKOHOLEN

Straight-chain, primary alcohols are prepared by reacting straight-chain 1-chloroalkanes having 6 to 20 carbon atoms with alkali salts of monocarboxylic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of monocarboxylic acids or alcohols based upon the alkali salt of the car...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: KETT,HARALD, KAUOLD,MANFRED,DR
Format: Patent
Sprache:ger
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:Straight-chain, primary alcohols are prepared by reacting straight-chain 1-chloroalkanes having 6 to 20 carbon atoms with alkali salts of monocarboxylic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of monocarboxylic acids or alcohols based upon the alkali salt of the carboxylic acid and at temperatures ranging from 150 DEG to 300 DEG C. The esters formed are saponified in alkaline medium to the straight-chain, primary alcohols and separated.