19-nor-neriifoline prodn - by photolytic decarbonyl-ation of peruvoside

19-Nor-neriifoline (I; R = H) is prepd. by subjecting peruvoside (I; R = CHO) to photolysis in an inert solvent, opt. in the presence of a photosensitiser. 19-Nor-neriifoline has the therapeutic properties of peruvoside (a cadioglycoside without effects on heart rate, stimulant and conductive system...

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Hauptverfasser: SCHORSCHER, ERNST., 6100 DARMSTADT-ARHEILGEN, SEITZ, GEORG. DR., 6100 DARMSTADT, SCHLIEP, HANS-JOCHEN., 6103 GRIESHEIM
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Sprache:eng ; ger
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Zusammenfassung:19-Nor-neriifoline (I; R = H) is prepd. by subjecting peruvoside (I; R = CHO) to photolysis in an inert solvent, opt. in the presence of a photosensitiser. 19-Nor-neriifoline has the therapeutic properties of peruvoside (a cadioglycoside without effects on heart rate, stimulant and conductive systems and diuresis) with the advantage of very high resorption after enternal administration.