Water dilutable binder for preparing aqueous thixotropic paints useful for coating plastics, contains rheological control agent based on chlorinated olefin

The binder contains a rheological control agent based on a chlorinated olefin. A water dilutable binder, for the preparation of aqueous thixotropic paints, contains a rheological control agent based on chlorinated olefin. Preparation of the RCA involves free radical polymerization of: (A) 20-90 wt.%...

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Hauptverfasser: DIRKING, THEODORA, ALLARD, MAXIME, RINK, HEINZ-PETER, BORGHOLTE, HARALD
Format: Patent
Sprache:eng ; ger
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Zusammenfassung:The binder contains a rheological control agent based on a chlorinated olefin. A water dilutable binder, for the preparation of aqueous thixotropic paints, contains a rheological control agent based on chlorinated olefin. Preparation of the RCA involves free radical polymerization of: (A) 20-90 wt.% of (wt.%) of a mixture of: (a1) acrylic acid, methacrylic acid or a mixture of these (3-50); and (a2) ethylenically unsaturated monomers different from (a1) or a mixture of these (50-97); in the presence of (B) a chlorine containing polyolefin of Cl content 1-50 wt.% relative to the polyolefin; and (C) a free radical former or a mixture of formers. After neutralization of at least 20% of its carboxyl groups the polymerisation product is dispersed in water, so that the sum of the wt.% contents of components (A), (B),(C), (a1) and (a2) is 100 wt.%. The composition of the mixture of (a1) and (a2) is so selected that on exclusive polymerization the mixture of (a1) and (a2) contains a polymerizate having a glass transition temperature of 0-150 deg C, 0.04-1.0 milliequivalents of one or more of the functional groups: COOH, -OH, -NR3, -CN, -CONH2, -CO-, NHCONH-, -OCONH-, OPO3H, -OSO3H, -R-O-R- (where R = an organic residue) and can be substituted by 0-50 wt.% of one or more of the following cycloaliphatic groups having at least one 1-12C alkyl group: cyclopentyl, cyclohexyl, perhydronaphthyl, perhydroanthracyl, perhydrophenanthryl, adamantyl, isobornyl, bicyclohexyl, bicycloheptyl, bicyclooctyl, bicyclononyl, bicyclodecyl, bicycloundecyl or bicyclododecyl. Independent claims are also included for: (1) aqueous paints containing at least one water dilutable binder as above; and (2) a process for priming or single layer coating of plastics bases, e.g. polypropylene bases, in which the aqueous paint is applied to the base. Die Erfindung betrifft wasserverdünnbare Rheologiesteuerungsmittel für wäßrige Lacke, die herstellbar sind, indem DOLLAR A (A) 20 bis 90 Gew.-% einer Mischung aus DOLLAR A (a1) 3 bis 50 Gew.-% Acrylsäure, Methacrylsäure oder einer Mischung aus Acrylsäure und Methacrylsäure und DOLLAR A (a2) 50 bis 97 Gew.-% eines ethylenisch ungesättigten Monomeren oder einer Mischung aus ethylenisch ungesättigten Monomeren, DOLLAR A in Gegenwart von DOLLAR A (B) 9,9 bis 79,9 Gew.-% eines chlorhaltigen Polyolefins mit einem Chlorgehalt von 1 bis 50 Gew.-%, bezogen auf das Polyolefin, und DOLLAR A (C) 0,1 bis 10 Gew.-% eines Radikalbildners oder einer Mischung aus Radika