Amino-alkylenoxidfunktionelle Organosiliciumverbindungen, deren Herstellung und Verwendung
New amino-alkyleneoxide-functional organosilicon compounds containing siloxane units are prepared by reacting an organosilicon compound containing at least one Si-bonded H atom with an amine. The amino-alkyleneoxide-functional organosilicon compounds contain (a) siloxane units of formula RaSi(OR )bO...
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Zusammenfassung: | New amino-alkyleneoxide-functional organosilicon compounds containing siloxane units are prepared by reacting an organosilicon compound containing at least one Si-bonded H atom with an amine. The amino-alkyleneoxide-functional organosilicon compounds contain (a) siloxane units of formula RaSi(OR )bO(4-a-b)/2; and (b) units of formula ARcSiO(4-c-1)/2, and/or O(4-c-1)/2RcSi-A -SiRcO(4-c-1)/2. R = 1-200C hydrocarbon optionally substituted by halogen, alkoxy or OH and optionally interrupted by one or more O; R = 1-8C alkyl optionally interrupted by one or more O; a, b = 0, 1, 2 or 3, with the proviso that a + b ≤ 3; c = 0, 1 or 2, especially 2; A = a group of formula -R N(R )H1-z-(CR 2-R )z (IV); A = -R -N(R )-R -; R = 2-12C hydrocarbylene; R = -(CH2CH2O)o-(C3H6O)p-((CH2)4O)q-R ; R = H, 1-22C alkyl, -SiRx(OR )y or -COR ; x, y = 0, 1, 2 or 3, with the proviso that x + y = 3; R = 1-8C alkyl; o, p and q = 0 or 1-200, especially 0 or 1-35, with o + p + q greater than 0; R = H or 1-8C alkyl; R = H or -CR -C(R )2 or -C equivalent to CR ; and R = as for R Preparation of (I) is by reaction in presence of a catalyst promoting addition of Si-bonded H to C-C multiple bonds of compound of formula HdRe(OR )f-SiO(4-e-d-f)/2 (II) with an amine having at least one R other than H and of formula R |
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