Verfahren zur Herstellung von Polymeren mit einer Oxetanylgruppe an der Seitenkette

Polymers having an oxetanyl group on the side chain and being represented by the following formula (2) are provided. They are usable for reactions such as ring-opening reaction and addition reaction. The process comprises subjecting to anionic ring-opening polymerization a 3-[(oxiranylmethoxy)methyl...

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Hauptverfasser: KURIYAMA, AKIRA, SASAKI, HIROSHI, KAKUCHI, TOYOJI
Format: Patent
Sprache:ger
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Zusammenfassung:Polymers having an oxetanyl group on the side chain and being represented by the following formula (2) are provided. They are usable for reactions such as ring-opening reaction and addition reaction. The process comprises subjecting to anionic ring-opening polymerization a 3-[(oxiranylmethoxy)methyl]oxetane monomer represented by the following formula (1) alone or together with other monomer containing an epoxy group:wherein A represents a hydrogen atom or an alkyl group of 1-6 carbon atoms,wherein A is the same as above, and R represents a hydrogen atom, a chloromethyl group, straight chain alkyl group or branched chain alkylene group of 1-12 carbon atoms, phenyl group, straight or branched chain alkyloxymethyl group of 1-12 carbon atoms or phenoxymethyl group, and n and m each represent a molar fraction, n being 100-1 mol %, m being 0-99 mol % with n+m=100.