Silyl substituted indanone production for use in metallocene catalysts

A process for the production of substituted indanones of formula (Ia) and (Ib) comprises reacting compounds of formula (IIa) or (IIb) respectively in one step with a compound of formula (III) in the presence of a Friedel-Crafts catalyst. H2C=C(C(O)X)-R (III) R -R = hydrogen, 1-4C alkyl, 1 - 4 C fluo...

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Hauptverfasser: RIEGER, BERNHARD., 89075 ULM, DE, TRUEBENBACH, PETER., 67065 LUDWIGSHAFEN, DE, WAGNER, JUERGEN MATTHAEUS., 89160 DORNSTADT, DE, DIETRICH, ULF, 89079 ULM, DE, MUELLER, HANS-JOACHIM., 67269 GRUENSTADT, DE
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creator RIEGER, BERNHARD., 89075 ULM, DE
TRUEBENBACH, PETER., 67065 LUDWIGSHAFEN, DE
WAGNER, JUERGEN MATTHAEUS., 89160 DORNSTADT, DE
DIETRICH, ULF, 89079 ULM, DE
MUELLER, HANS-JOACHIM., 67269 GRUENSTADT, DE
description A process for the production of substituted indanones of formula (Ia) and (Ib) comprises reacting compounds of formula (IIa) or (IIb) respectively in one step with a compound of formula (III) in the presence of a Friedel-Crafts catalyst. H2C=C(C(O)X)-R (III) R -R = hydrogen, 1-4C alkyl, 1 - 4 C fluoroalkyl or 1 - 4 C alkylsilyl, or silyl, phenyl or benzyl; or R and R plus attached carbon atoms may form a benzene ring; R = 1-10C alkyl, phenyl or (1-4C alkyl)-phenyl; and X = chlorine, bromine or iodine.
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title Silyl substituted indanone production for use in metallocene catalysts
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