Preparation of poly:cyclic N=heterocyclic compounds of perinone type with high productivity and selectivity
Preparation of polycyclic N-heterocyclic compounds of formula (I) by reacting aromatic dicarboxylic acids of formula (II) or their anhydrides or esters with aromatic diamines of formula (III), reaction is carried out in a medium containing ethylene glycol at > 100 deg C; in which A = 1,2-phenylen...
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Zusammenfassung: | Preparation of polycyclic N-heterocyclic compounds of formula (I) by reacting aromatic dicarboxylic acids of formula (II) or their anhydrides or esters with aromatic diamines of formula (III), reaction is carried out in a medium containing ethylene glycol at > 100 deg C; in which A = 1,2-phenylene, 2,3- or 1,8-naphthylene or arylene of > 2 condensed benzene rings, optionally mono- or poly-substituted by Y; Y = 1-6 carbon (C) alkyl, halogen, nitro (NO2), 6-10 C aryl, 6-10 C aryloxysulphonyl, hydroxy (OH), 4-9 C alkoxy, 6-10 C aryloxy, aminosulphonyl (optionally substituted by 1-6 C alkyl or 6-10 C aryl) or a condensed cycloaliphatic or heterocyclic group; B = ortho-phenylene, ortho-naphthylene, peri-(1,8)-naphthylene or arylene of > 2 condensed benzene rings; the arylene groups A and B of > 2 condensed benzene rings are bridged in the ortho-position or corresponding to a peri-position in naphthalene. |
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