Verfahren zur Herstellung von Aziridinen

The prodn. of aziridines of formula (I), in which R -R = H, 1-8C alkyl, 3-8C cycloalkyl or aryl, and R = H, 1-8C alkyl, hydroxyalkyl or aminoalkyl, 3-8C cycloalkyl, aryl or benzyl, comprises the dehydration/cyclisation of alkanolamines of formula (II) in the gas phase at 200-600 degrees C and 0.001-...

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Hauptverfasser: STEUERLE, ULRICH., 69124 HEIDELBERG, DE, DINGERDISSEN, UWE., 64342 SEEHEIM-JUGENHEIM, DE, TRUEBENBACH, PETER., 67065 LUDWIGSHAFEN, DE, LAUTH, GUENTER, DR., 23562 LUEBECK, DE
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Sprache:ger
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Zusammenfassung:The prodn. of aziridines of formula (I), in which R -R = H, 1-8C alkyl, 3-8C cycloalkyl or aryl, and R = H, 1-8C alkyl, hydroxyalkyl or aminoalkyl, 3-8C cycloalkyl, aryl or benzyl, comprises the dehydration/cyclisation of alkanolamines of formula (II) in the gas phase at 200-600 degrees C and 0.001-5 bar on heterogeneous catalysts (III) in the form of presintered moulded pellets.