Verfahren zur gleichzeitigen Herstellung von Alkalialkoholaten und loeslichen beta-Diketonkomplexverbindungen des 3-wertigen Titans

Tetravalent titanium alcoholate-beta diketone complexes, e.g. titanium isopropylate-triacetylacetonate, are reacted with an alkali metal amalgam in a non-polar solvent to reduce the titanium to trivalent state, forming, for example, titanium triacetylacetonate and sodium isopropylate. The sodium iso...

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Bibliographische Detailangaben
Hauptverfasser:	HAUCK,GERHARD,DR, TERMIN,ERICH,DR
Format:	Patent
Sprache:	ger
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP
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Zusammenfassung:	Tetravalent titanium alcoholate-beta diketone complexes, e.g. titanium isopropylate-triacetylacetonate, are reacted with an alkali metal amalgam in a non-polar solvent to reduce the titanium to trivalent state, forming, for example, titanium triacetylacetonate and sodium isopropylate. The sodium isopropylate is a crystalline precipitate which can be removed by filtration; the amalgam can be decanted off and reused, as in alkali metal chloride electrolysis, to restore its alkali metal content so as to be ready for re-cycling.