Verfahren zur Herstellung von als optische Aufheller verwendbaren Azolverbindungen
The invention comprises compounds of the formula and the production of compounds of the formula where R is a 4,41-stilbene radical, A is an o-phenylene radical and X is 0 or 5, by heating HOOC-R-COOH with HX-A-NH2.(HCl)m (where m is 0 or 1) and a halogenating agent capable of converting COOH to ac...
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creator | SIGMUND BLOOM,MELVIN |
description | The invention comprises compounds of the formula and the production of compounds of the formula where R is a 4,41-stilbene radical, A is an o-phenylene radical and X is 0 or 5, by heating HOOC-R-COOH with HX-A-NH2.(HCl)m (where m is 0 or 1) and a halogenating agent capable of converting COOH to acid halide, e.g. POCl3, to form an intermediate condensation product, and then refluxing to form the product. A solvent may be used, e.g. 1,2,4-trichlorobenzene. Both R and/or A may be substituted; many possible substituents are given. In examples, X is 0 or S and R and A are unsubstituted; and X is 0, R is unsubstituted, and A is phenyl-substituted. The products may be mixed with soaps or detergents for increasing fabric brightness or whiteness. |
format | Patent |
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A solvent may be used, e.g. 1,2,4-trichlorobenzene. Both R and/or A may be substituted; many possible substituents are given. In examples, X is 0 or S and R and A are unsubstituted; and X is 0, R is unsubstituted, and A is phenyl-substituted. The products may be mixed with soaps or detergents for increasing fabric brightness or whiteness.</description><language>ger</language><subject>BLEACHING LEATHER OR FURS ; CHEMISTRY ; DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS,YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS ; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR ; HETEROCYCLIC COMPOUNDS ; LAUNDERING ; METALLURGY ; ORGANIC CHEMISTRY ; TEXTILES ; TREATMENT OF TEXTILES OR THE LIKE</subject><creationdate>1968</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19681205&DB=EPODOC&CC=DE&NR=1445699A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25543,76293</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19681205&DB=EPODOC&CC=DE&NR=1445699A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>SIGMUND BLOOM,MELVIN</creatorcontrib><title>Verfahren zur Herstellung von als optische Aufheller verwendbaren Azolverbindungen</title><description>The invention comprises compounds of the formula <FORM:1072919/C2/1> and the production of compounds of the formula <FORM:1072919/C2/2> where R is a 4,41-stilbene radical, A is an o-phenylene radical and X is 0 or 5, by heating HOOC-R-COOH with HX-A-NH2.(HCl)m (where m is 0 or 1) and a halogenating agent capable of converting COOH to acid halide, e.g. POCl3, to form an intermediate condensation product, and then refluxing to form the product. A solvent may be used, e.g. 1,2,4-trichlorobenzene. Both R and/or A may be substituted; many possible substituents are given. In examples, X is 0 or S and R and A are unsubstituted; and X is 0, R is unsubstituted, and A is phenyl-substituted. The products may be mixed with soaps or detergents for increasing fabric brightness or whiteness.</description><subject>BLEACHING LEATHER OR FURS</subject><subject>CHEMISTRY</subject><subject>DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS,YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS</subject><subject>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>LAUNDERING</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>TEXTILES</subject><subject>TREATMENT OF TEXTILES OR THE LIKE</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>1968</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZAgKSy1KS8woSs1TqCotUvBILSouSc3JKc1LVyjLz1NIzClWyC8oySxOzkhVcCxNywDKpRYplKUWlafmpSQlgvQ5VuXnAAWSMvNSgNpS83gYWNOA-lJ5oTQ3g4Kba4izh25qQX58anFBYnJqXmpJvIuroYmJqZmlpaOhMRFKAA9qOI4</recordid><startdate>19681205</startdate><enddate>19681205</enddate><creator>SIGMUND BLOOM,MELVIN</creator><scope>EVB</scope></search><sort><creationdate>19681205</creationdate><title>Verfahren zur Herstellung von als optische Aufheller verwendbaren Azolverbindungen</title><author>SIGMUND BLOOM,MELVIN</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_DE1445699A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>ger</language><creationdate>1968</creationdate><topic>BLEACHING LEATHER OR FURS</topic><topic>CHEMISTRY</topic><topic>DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS,YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS</topic><topic>FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>LAUNDERING</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>TEXTILES</topic><topic>TREATMENT OF TEXTILES OR THE LIKE</topic><toplevel>online_resources</toplevel><creatorcontrib>SIGMUND BLOOM,MELVIN</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>SIGMUND BLOOM,MELVIN</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Verfahren zur Herstellung von als optische Aufheller verwendbaren Azolverbindungen</title><date>1968-12-05</date><risdate>1968</risdate><abstract>The invention comprises compounds of the formula <FORM:1072919/C2/1> and the production of compounds of the formula <FORM:1072919/C2/2> where R is a 4,41-stilbene radical, A is an o-phenylene radical and X is 0 or 5, by heating HOOC-R-COOH with HX-A-NH2.(HCl)m (where m is 0 or 1) and a halogenating agent capable of converting COOH to acid halide, e.g. POCl3, to form an intermediate condensation product, and then refluxing to form the product. A solvent may be used, e.g. 1,2,4-trichlorobenzene. Both R and/or A may be substituted; many possible substituents are given. In examples, X is 0 or S and R and A are unsubstituted; and X is 0, R is unsubstituted, and A is phenyl-substituted. The products may be mixed with soaps or detergents for increasing fabric brightness or whiteness.</abstract><oa>free_for_read</oa></addata></record> |
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subjects | BLEACHING LEATHER OR FURS CHEMISTRY DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS,YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR HETEROCYCLIC COMPOUNDS LAUNDERING METALLURGY ORGANIC CHEMISTRY TEXTILES TREATMENT OF TEXTILES OR THE LIKE |
title | Verfahren zur Herstellung von als optische Aufheller verwendbaren Azolverbindungen |
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