Verfahren zur Herstellung hochmolekularer, linearer Polycarbonate

Polycarbonates are made by a continuous process by reacting an organic dihydroxy compound with phosgene and/or a bis-chlorocarbonic acid ester of an organic dihydroxy compound in the presence of an organic monohydroxy compound, an acid-binding agent, a tertiary amine of a quaternary ammonium compound (as catalyst) and an inert solvent which dissolves the polycarbonate. A reducing agent may also be present. The process may be effected in four or five vessels connected in series and each provided with stirrers and the catalyst may be added to the second or third vessel. Alternatively, it may be effected in a vertical reaction tube fed at the top with a solution of the dihydroxy compound in part of the acid-binding agent, the monohydric compound and part of the phosgene, at four intermediate points with additional phosgene, and at a lower intermediate point with the catalyst and further acid-binding agent. The polycarbonate solutions produced by the process may be separated from the reaction mixture by a liquid centrifuge and continuously washed and, if desired, dyestuffs pigments or stabilizers may be added. The solvent may then be removed from the polycarbonate by evaporation in a worm press or by steam distillation. Alternatively, the polycarbonate may be precipitated by the addition of a non-solvent (e.g. an aliphatic hydrocarbon, alcohol or ketone). The dihydroxy compound may be a dihydric phenol (e.g. a bis-phenol, or a dihydroxy benzene, naphthalene, diphenyl or quinoline), a phenol alcohol, an aliphatic dihydric alcohol (e.g. an alkylene-, oxyalkylene or thioalkylene glycol), a cycloaliphatic dihydric alcohol or an aromatic dihydric alcohol. The organic monohydroxy compound may be phenol, a cresol, p-isopropyl phenol, p-tertiary-butyl phenol or p-chlorophenol. The acid-binding agent is preferably an aqueous solution of sodium hydroxide but a tertiary amine may also be used. The organic solvent may be methylene chloride, chloroform, ethylene chloride, chlorobenzene, benzene, toluene or xylene. Examples describe the production of the polycarbonate of bis-phenol A chain-stopped with p-tert.-butyl phenol. Specifications 772,627, 808,485, 808,486 and 808,490 are referred to.