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Compounds prepared by condensing a polyoxyalkylene compound with a di-epoxide have the general formula: wherein R5 is an alkylene group of at least 2 carbon atoms, R6 is the group -CH2-O-(CH2)n\t -O-CH2- where n is 1 to 4, R7 is hydrogen or the group and x and y are integers of at least 2. In an e...
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Zusammenfassung: | Compounds prepared by condensing a polyoxyalkylene compound with a di-epoxide have the general formula: wherein R5 is an alkylene group of at least 2 carbon atoms, R6 is the group -CH2-O-(CH2)n\t -O-CH2- where n is 1 to 4, R7 is hydrogen or the group and x and y are integers of at least 2. In an example, polyethylene glycol (M.W. 300) is condensed with 1;2- bis (21;31-epoxypropoxy) ethane in aqueous potassium hydroxide and in an atmosphere of nitrogen. Specifications 548,019, 592,676, 600,058, 748,745, 748,750, 789,823, 920,637 and Belgian Specifications 493,464, 568,687, 571,916 and 571,917 also are referred to. ALSO: Polymers are prepared by condensing a polyoxyalkylene compound with a diepoxide of the formula:-R-(CH2)n-R where R is a 2;3-epoxypropoxy group and n is 1 to 4. Examples are given of the condensation of polyethylene glycol with 1;2-di(21;31-epoxypropoxy)ethane or 1;4-di(21;31-epoxypropoxy)butane by adding the epoxy compound to a heated mixture of the polyethylene glycol in aqueous potassium hydroxide in an atmosphere of nitrogen. Specification 548,019, 592,676, 600,058, 748,745, 748,750, 789,823, 920,637 and Belgian Specifications 493,464, 568,687, 571,916 and 571,917 also are referred to. |
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