MATERIALS BASED ON MULTI-METAL OXIDES
Multimetal oxide compsn. of formula (I) is new: (A)p(B)q (I); A = Mo12X aX bX cX dSeX fOx; B = X 12X gX hOy; X = P, As, B, Ge and/or Si; X = V, Nb and/or W; X = H, ≤ 97 mole-% of which may be replaced by K, Rb, Ca and/or NH4; X = Sb and/or Bi; X = Re and/or Rh; X = Mo, W, Nb and/or Ta; X = Fe, Co, N...
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Zusammenfassung: | Multimetal oxide compsn. of formula (I) is new: (A)p(B)q (I); A = Mo12X aX bX cX dSeX fOx; B = X 12X gX hOy; X = P, As, B, Ge and/or Si; X = V, Nb and/or W; X = H, ≤ 97 mole-% of which may be replaced by K, Rb, Ca and/or NH4; X = Sb and/or Bi; X = Re and/or Rh; X = Mo, W, Nb and/or Ta; X = Fe, Co, Ni, Rh, Ru, Mg, Ca, Sr, Ba, Zn, Cd, Hg, Y, Sc and lanthanides, pref. Ce, La and Eu; X = Li, Na, K, Rb, Cs and/or NH4; a = 1-6; b, d = 0-6; c = 3-5; e, f = 0-3; g = 0-20; h = 0-4; x, y = values depending on the valency and content of elements other than 0; p, q = values other than 0, with p/q = 12:0.1 to 12:48; the (A)p and (B)q fractions are each in the form of 3D A and B zones, which differ in chemical compsn. from their local surroundings, and the relative distribution of the A and B zones is as in a finely-divided mixt. of A and B. |
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