METHOD OF FERROCHROME CATALYST PRODUCTION FOR CARBON MONOXIDE CONVERSION BY MEANS OF WATER WAPOUR

The solution concerns a method of production of ferrochrome catalyser for high-temperature conversion of carbon monoxide by water vapour by means of precipitation of solutions of technologically clean iron sulphates by solutions of ammonium or alkaline carbonates, by promoting of precipitated basic...

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Hauptverfasser: KUBAL PETR ,CS, LOUKOTA JIRI,CS, SOKOL LUDVIK CSC.,CS, KANE MILAN,CS, NOVOTNY JIRI,CS
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creator KUBAL PETR ,CS
LOUKOTA JIRI,CS
SOKOL LUDVIK CSC.,CS
KANE MILAN,CS
NOVOTNY JIRI,CS
description The solution concerns a method of production of ferrochrome catalyser for high-temperature conversion of carbon monoxide by water vapour by means of precipitation of solutions of technologically clean iron sulphates by solutions of ammonium or alkaline carbonates, by promoting of precipitated basic carbonates by chromium compounds, and by their shaping in tablets. The solution of iron sulphate containing from 85 to 95 g of Fe/l and at most 50 percent of final contents from 8 to 10 percent by weight of Cr2O3 in catalyser, with content of titan below 0.1 percent by weight and/or nickel below 0.05 percent by weight and/or manganese below 0.1 percent by weight is introduced into the solution of carbonates containing from 3.8 to 4.7 val NH3 or basic hydroxyls/l and from 3.8 to 5.5 val CO2/l at a temperature of 45 to 65 degrees C. The obtained suspension is diluted by water 1:1 and decanted by vapour condensate, optimally with conductivity of 15 micro siemens. After filtering it is peptised and promoted by simultaneous washing after mixing with 40 percent of reversing granulate by the solution of chromium oxide to by suspension selected ferrous sediments to content of Cr2O3 in catalyser from 8 to 10 percent by weight. The obtained granulate is dried, heat processed and shaped into the form of tablets. The originated catalyser shows higher activity at conversion of carbon monoxide by water vapour than catalyser used up to the present.
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The solution of iron sulphate containing from 85 to 95 g of Fe/l and at most 50 percent of final contents from 8 to 10 percent by weight of Cr2O3 in catalyser, with content of titan below 0.1 percent by weight and/or nickel below 0.05 percent by weight and/or manganese below 0.1 percent by weight is introduced into the solution of carbonates containing from 3.8 to 4.7 val NH3 or basic hydroxyls/l and from 3.8 to 5.5 val CO2/l at a temperature of 45 to 65 degrees C. The obtained suspension is diluted by water 1:1 and decanted by vapour condensate, optimally with conductivity of 15 micro siemens. After filtering it is peptised and promoted by simultaneous washing after mixing with 40 percent of reversing granulate by the solution of chromium oxide to by suspension selected ferrous sediments to content of Cr2O3 in catalyser from 8 to 10 percent by weight. The obtained granulate is dried, heat processed and shaped into the form of tablets. The originated catalyser shows higher activity at conversion of carbon monoxide by water vapour than catalyser used up to the present.</abstract><edition>5</edition><oa>free_for_read</oa></addata></record>
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS
COMPOUNDS THEREOF
FUELS
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
INORGANIC CHEMISTRY
LUBRICANTS
METALLURGY
NON-METALLIC ELEMENTS
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLEGASES CONTAINING CARBON MONOXIDE
TECHNICAL GASES CONTAINING CARBON MONOXIDE
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE
THEIR RELEVANT APPARATUS
TRANSPORTING
title METHOD OF FERROCHROME CATALYST PRODUCTION FOR CARBON MONOXIDE CONVERSION BY MEANS OF WATER WAPOUR
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