Imidazoline salt, rhodium complex of carbohydrate derivative and its preparation method

Imidazoline salt, rhodium complex of carbohydrate derivative and its preparation method

The invention discloses a making method of rhodium complex compound of imidazoline and coordination of carbohydrate derivant, which comprises the following steps: reacting N,N'-di (methyl 3-deoxygenation-4, 6-O-benzyl crossing base-alpha-D-altronic pyran glycoside-3-base) ethanediamine and 40 m...

Ausführliche Beschreibung

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Bibliographische Detailangaben
1. Verfasser: JICHENG,TONG SHI
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
DERIVATIVES THEREOF
METALLURGY
NUCLEIC ACIDS
NUCLEOSIDES
NUCLEOTIDES
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SUGARS
THEIR RELEVANT APPARATUS
TRANSPORTING
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Beschreibung
Zusammenfassung:The invention discloses a making method of rhodium complex compound of imidazoline and coordination of carbohydrate derivant, which comprises the following steps: reacting N,N'-di (methyl 3-deoxygenation-4, 6-O-benzyl crossing base-alpha-D-altronic pyran glycoside-3-base) ethanediamine and 40 ml ammonium chloride in the triethoxymethane for 3-4. 2h; cooling; filtering; washing through petroleum ether to obtain chiral imidazoline ligand; blending the ligand and [RhCl(COD)]2 and NaOtBu to react in the 20ml THF for 48h at 45 deg. c; filtering; purifying through column chromatography to obtain the product as high-property catalyst.