Catalyst complex for catalyzing esterification and ester exchange reactions and method for esterification/trans-esterification using the same

The present invention relates to a novel catalyst complex for catalysing esterification and trans-esterification reactions, comprising: (i) a polymeric titanium glycolate having the formula [TiO4(CH2)4]n wherein n = 1 to 200; and (ii) an alkali metal glycolate; wherein the molar ratio of the polymer...

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Bibliographische Detailangaben
1. Verfasser:	SIDDIQUI J. A.,AL-LUHAIDAN K.,GUTMANN R.,URIA A.,SCHWEIZER M.,AL-FARHOOD B.,FRITZ A
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	The present invention relates to a novel catalyst complex for catalysing esterification and trans-esterification reactions, comprising: (i) a polymeric titanium glycolate having the formula [TiO4(CH2)4]n wherein n = 1 to 200; and (ii) an alkali metal glycolate; wherein the molar ratio of the polymeric titanium glycolate and the alkali metal glycolate is about 1.25:1 to about 100:1, preferably about 1.25:1 to about 10:1; and to a process for esterification of a dicarboxylic acid compound and an dialcoholic compound, followed by polycondensation to form a polyester.