In mold addition polymerization composition of norbornene-type monomers and its crosslinking addition polymer

公开了用于多环烯烃的本体加成聚合的反应物组合物,多环烯烃例如降冰片烯、甲基降冰片烯、乙基降冰片烯、丁基降冰片烯、或己基降冰片烯,1,2,3,4,4a,5,8,8a-八氢-1,4:5,8-二亚甲基萘、5,5'-(1,2-乙二基)双二环[2.2.1]庚-2-烯、和1,4,4a,4b,5,8,8a,8b-八氢-1,4:5,8-二亚甲基亚二苯基。聚合可在反应注射成型过程中进行,得到具有高玻璃化转变温度的热塑性和热固性聚合物模塑制品。 A catalyst system and a process for the bulk addition polymerization or of polyc...

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Hauptverfasser: RHODES LARRY F, GOODALL BRIAN L, BELL ANDREW, FONDRAN JOHN C
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GOODALL BRIAN L
BELL ANDREW
FONDRAN JOHN C
description 公开了用于多环烯烃的本体加成聚合的反应物组合物,多环烯烃例如降冰片烯、甲基降冰片烯、乙基降冰片烯、丁基降冰片烯、或己基降冰片烯,1,2,3,4,4a,5,8,8a-八氢-1,4:5,8-二亚甲基萘、5,5'-(1,2-乙二基)双二环[2.2.1]庚-2-烯、和1,4,4a,4b,5,8,8a,8b-八氢-1,4:5,8-二亚甲基亚二苯基。聚合可在反应注射成型过程中进行,得到具有高玻璃化转变温度的热塑性和热固性聚合物模塑制品。 A catalyst system and a process for the bulk addition polymerization or of polycyclic olefins, such as norbornene, methylnorbornene, ethylnorbornene, butylnorbornene or hexylnorbornene, 1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonapthalene, 5,5'-(1,2-ethanediyl)bisbicyclo[2.2.1]hept-2-ene, and 1,4,4a,4b,5,8,8a,8b-octahydro-1,4:5,8-dimethanobiphenylene are disclosed. The catalyst includes an organonickel or organopalladium transition metal procatalyst and an activator compound. Polymerization can be carried out in a reaction injection molding process to yield thermoplastic and thermoset molded polymeric articles possessing high glass transition temperatures.
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The catalyst includes an organonickel or organopalladium transition metal procatalyst and an activator compound. Polymerization can be carried out in a reaction injection molding process to yield thermoplastic and thermoset molded polymeric articles possessing high glass transition temperatures.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
CHEMISTRY
COMPOSITIONS BASED THEREON
INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PERFORMING OPERATIONS
SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR
SHAPING OR JOINING OF PLASTICS
THEIR PREPARATION OR CHEMICAL WORKING-UP
TRANSPORTING
WORKING OF PLASTICS
WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL
title In mold addition polymerization composition of norbornene-type monomers and its crosslinking addition polymer
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