In mold addition polymerization composition of norbornene-type monomers and its crosslinking addition polymer

公开了用于多环烯烃的本体加成聚合的反应物组合物，多环烯烃例如降冰片烯、甲基降冰片烯、乙基降冰片烯、丁基降冰片烯、或己基降冰片烯，1，2，3，4，4a，5，8，8a-八氢-1，4：5，8-二亚甲基萘、5，5'-(1，2-乙二基)双二环[2.2.1]庚-2-烯、和1，4，4a，4b，5，8，8a，8b-八氢-1，4：5，8-二亚甲基亚二苯基。聚合可在反应注射成型过程中进行，得到具有高玻璃化转变温度的热塑性和热固性聚合物模塑制品。 A catalyst system and a process for the bulk addition polymerization or of polyc...

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Bibliographische Detailangaben
Hauptverfasser:	RHODES LARRY F, GOODALL BRIAN L, BELL ANDREW, FONDRAN JOHN C
Format:	Patent
Sprache:	chi ; eng
Schlagworte:	AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING CHEMISTRY COMPOSITIONS BASED THEREON INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR SHAPING OR JOINING OF PLASTICS THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING WORKING OF PLASTICS WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL
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Beschreibung
Zusammenfassung:	公开了用于多环烯烃的本体加成聚合的反应物组合物，多环烯烃例如降冰片烯、甲基降冰片烯、乙基降冰片烯、丁基降冰片烯、或己基降冰片烯，1，2，3，4，4a，5，8，8a-八氢-1，4：5，8-二亚甲基萘、5，5'-(1，2-乙二基)双二环[2.2.1]庚-2-烯、和1，4，4a，4b，5，8，8a，8b-八氢-1，4：5，8-二亚甲基亚二苯基。聚合可在反应注射成型过程中进行，得到具有高玻璃化转变温度的热塑性和热固性聚合物模塑制品。 A catalyst system and a process for the bulk addition polymerization or of polycyclic olefins, such as norbornene, methylnorbornene, ethylnorbornene, butylnorbornene or hexylnorbornene, 1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonapthalene, 5,5'-(1,2-ethanediyl)bisbicyclo[2.2.1]hept-2-ene, and 1,4,4a,4b,5,8,8a,8b-octahydro-1,4:5,8-dimethanobiphenylene are disclosed. The catalyst includes an organonickel or organopalladium transition metal procatalyst and an activator compound. Polymerization can be carried out in a reaction injection molding process to yield thermoplastic and thermoset molded polymeric articles possessing high glass transition temperatures.