Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same

The present invention relates to a novel fulvene compound and a preparation method thereof, and more particularly to a fulvene compound having substituted groups in the 2- and 5-positions, prepared from an unsaturated ketone having a substituted group in the beta-position and a halogen atom in the a...

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1. Verfasser: PARK YOUNG-WHAN,LEE SI-GEUN,HONG SUNG-DON,SONG KWANG-HO,JEONG BOONG-GOON,NAM DAE-WOO,LEE BUN-YEOL,LEE CHOONG-HOON,LEE HYO-SUN
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Sprache:eng
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Zusammenfassung:The present invention relates to a novel fulvene compound and a preparation method thereof, and more particularly to a fulvene compound having substituted groups in the 2- and 5-positions, prepared from an unsaturated ketone having a substituted group in the beta-position and a halogen atom in the alpha-position, and a preparation method thereof. The present invention also relates to a metallocene catalyst having a substituted group in the alpha-position carbon of the bridge of the cyclopentadienyl group only by reaction of a fulvene compound and an anion group including the cyclopentadienyl group, and a preparation method of a polyolefin copolymer using the same.