A process for the preparation of cyclopropane carboxylic acids

A process for the preparation of cyclopropane carboxylic acids

Preparation of cyclopropane carboxylic acids usable as intermediates and of formula (II), wherein R1 represents halogen, preferably Cl or Br, or haloalkyl, preferably CF3, and X2 represents halogen, preferably Cl or Br, where R1 or X2 may be the same or different, and wherein the configuration of (I...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: H. KOLIND-ANDERSEN, P.D. KLEMMENSEN, I. WINCKELMANN
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:Preparation of cyclopropane carboxylic acids usable as intermediates and of formula (II), wherein R1 represents halogen, preferably Cl or Br, or haloalkyl, preferably CF3, and X2 represents halogen, preferably Cl or Br, where R1 or X2 may be the same or different, and wherein the configuration of (II) is predominantly Z for R1=CF3 and X2=Cl; by reacting, in the presence of a catalyst, a compound of formula (I), wherein R1 and X2 are as defined, and X1 represents halogen, preferably Cl or Br, where R1, X1 and X2 may be the same or different, with a compound which is a hydrogen donor.