Method for preparing polyolefins

A method is disclosed for preparing broad or bimodal molecular weight distribution polyolefins having a targeted property, such as, flow index, melt flow ratio, or weight fractions of higher or lower molecular weight components. The method uses a bimetallic catalyst containing a metallocene componen...

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Bibliographische Detailangaben
1. Verfasser: SCHREGENBERGER SANDRA D.,SHIRODKAR PRADEEP P.,DACKSON KEITH,MINK ROBERT I.,NOWLIN THOMAS E.,SCHURZKY KENNETH G
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:A method is disclosed for preparing broad or bimodal molecular weight distribution polyolefins having a targeted property, such as, flow index, melt flow ratio, or weight fractions of higher or lower molecular weight components. The method uses a bimetallic catalyst containing a metallocene component and a non-metallocene component, and the activities of the metallocene and non-metallocene portions are controlled by adjusting the ratio of organoaluminum and modified methylaluminoxane cocatalyst. The method allows for monitoring and adjustment of polyolefin properties on a real-time basis, as the polyolefin is forming.